01 settembre 13, 23:39 | #21 (permalink) Top | |
User Data registr.: 09-10-2012 Residenza: Como
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02 settembre 13, 11:37 | #22 (permalink) Top | |
User Data registr.: 22-09-2011 Residenza: Da qualche parte, laggiù
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__________________ "Mira alla luna. Anche se sbagli, atterrerai tra le stelle". (Cit. Les Brown.) | |
02 settembre 13, 12:39 | #24 (permalink) Top |
User Data registr.: 23-02-2013 Residenza: Valguarnera carropepe
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Qualche tipo di nitrometano aveva un colorante giallo come indicatore di sicurezza. In caso di contaminazione avrebbe virato al blu ol al verde indicando pericolo di esplosione. Ecco un estratto da un forum di "piccoli chimici" USA. Angus Chemicals , a subsidiary of Dow Chemical Co. since June of 2000 is the only domestic manufacturer of Nitromethane. Angus makes just one grade of 98.4% pure Nitromethane in a plant in Sterlington Louisiana for industrial use , car racing , and a small amount devoted to RC model use. Prospective resellers and manufacturers are subject to review and are eligible to receive bulk shipments only if approved by Angus. The Angus plant produces Nitroalkanes on an industrial scale by vapor phase nitration of Propane under pressure at up to 475 ºC. The resulting mixture of nitroparaffins , unreacted feed stock , and waste by products ( water, hydrogen , nitric oxide and carbon monoxide and dioxide ) are then separated by filtration , distillation , and other chemical processes into individual product lines and by products. Accordingly composition of the production yields 25 % Nitromethane , 10 % Nitroethane , 40 % 2-Nitropropane , and 15 % Nitropropane. Commercial Nitromethane thereby contains residual amounts of Nitroethane and Nitropropane isomers as impurities. The product also has trace amounts of Formaldehyde , Acetaldehyde , Methanol and Ethanol. Nitromethane itself is affected by photodecomposition , and breaks down slowly on exposure to light. Nitromethane is chemically stable when kept in the dark at room temperature sealed in brown bottles or cans. Some Nitromethane fuel is tinged yellow because it has an indicator dye in it. VP Racing Fuel brand Nitromethane has this yellow dye. The purpose of it is to alert you if it has been accidentally sensitized. Sensitized nitro does not burn , it explodes. If it turns blue or green it is sensitized. Chinese bulk manufacture of Nitromethane relies on the method of synthesis used for obtaining reagent grade product directly from precursors Dimethylsulfate and NaNO2 in a water slurry. It is obtained in 57 % yield when 1 mol of Dimethylsulfate is added to 1 mol NaNO2 in a saturated water solution and mixed cold until the first stage is completed when a second mol of of Nitrite is added. The reaction is carried at or below 20 ºC to limit formation of coproducts , primarily methyl nitrite and an aqueous solution of Na2SO4. The mixture is then distilled at reduced pressure. Nitromethane is initially obtained over 96 % pure , the primary contaminant being water. This and other residual by products are removed in a two stage batch distillation. The resulting product is then greater than 99 % having less than 0.1 % water. These processes are outlined in Vogels Practical Organic Chemistry 3rd Editon on pages 302 & 303. The lower yield preparative method using Chloracetic acid and NaNO2 is given on page 307. The purest Nitromethane is obtained as the sole product of the reaction of Methyl Iodide on Silver Nitrite. |
02 settembre 13, 13:15 | #25 (permalink) Top | |
User Data registr.: 22-09-2011 Residenza: Da qualche parte, laggiù
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__________________ "Mira alla luna. Anche se sbagli, atterrerai tra le stelle". (Cit. Les Brown.) | |
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